Product ID:9879178,N,N-DIMETHYL-P-PHENYLENEDIAMINE SULF.,SEE SUPPL DATA
MSDS Date:07/25/1997
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKLNB

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

N,N-DIMETHYL-P-PHENYLENEDIAMINE SULFATE

CAS: 536-47-0

LD50 LC50 Mixture:ORAL LD-50 (RAT): 100 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL IF INHALED. EYES:
CAUSES IRRITATION. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF
THE GASTROINTESTINAL TRACT .
Explanation of Carcinogenicity:(COMPONENTS PRESENT AT 0.1% OR MORE):
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE. AMERICAN
CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE.
NATIONAL TOXICOLOGY PROGRAM (NT P): NONE. OCCUPATIONAL SAFETY AND
HEALTH ADMINISTRATION (OSHA): NONE.
Effects of Overexposure:INHALATION: HARMFUL IF INHALED. EYES: CAUSES
IRRITATION. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF
THE GASTROINTESTINAL TRACT .
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTI ON. SKIN: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST
15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN
IRRITATION / AN ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL
ATTENTION. WASH CONT AMINATED CLOTHING BEFORE REUSE.
DESTROY/THOROUGHLY CLEAN CONTAMINATED SHOES. INGESTION: INDUCE
VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN/POISON CONTROL
CENTER AT ONCE.

Flash Point:COMBUSTIBL SOLID
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST-AIR MIXTURES.

Spill Release Procedures:COLLECT UP AND PUT IN A SUITABLE CONTAINER.
AVOID GENERATION OF DUST.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:KEEP CONTAINER CLOSED. USE WITH
ADEQUATE VENTILATION. MINIMIZE DUST GENERATION AND ACCUMULATION.
KEEP AWAY FROM SOURCES OF IGNITION.
Other Precautions:AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN,
AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. ROUTINE USE OF NONALKALINE (ACID) TYPE HAND CLEANER,
REGULAR CLEANING OF WORKING SURFACES, GLOVES, WILL MINIMIZE
POSSIBILITY OF SKIN REACTION.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS TO AN ACCEPTABLE LEVEL, AN APPROVED RESPIRATOR MUST
BE WORN. RESPIRATOR TYPE: DUST. IF RESPIRATORS ARE USED, A PROGRAM
SHOULD BE INSTITU TED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29
CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES APPROPRIATE FOR THE RISK OF
EXPOSURE.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
987 9178,N,N-DIMETHYL-P-PHENYLENEDIAMINE SULFATE FOR KODAK IMAGE GUARD
PROGRAM, KODAK MICROFILM PROCESSING PROGRAM

HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:NOT PROVIDED
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:NEGLIGIBLE
Spec Gravity:NOT AVAILABLE
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:APPRECIABLE
Appearance and Odor:PHYSICAL FORM: SOLID (POWDER) COLOR: GRAY ODOR:
SLIGHT
Percent Volatiles by Volume:NEGLIGIBLE

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:MATERIALS CONTAINING SIMILAR STRUCTURAL
GROUPS ARE NORMALLY STABLE.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF SULFUR, OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:INCINERATE. DISCHARGE, TREATMENT, OR DISPOSAL
MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER
CONTAINER IS EMPTIED.

Toxicological Information:ORAL LD-50 (RAT): 100 MG/KG ORAL LD-50
(MOUSE): 59 MG/KG SKIN IRRITATION: MODERATE SKIN
SENSITIZATION: NEGATIVE DERMAL LD-50: > 1.0 G/KG

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA FOR A CHEMICALLY SIMILAR MATERIAL HAS BEEN USED. IT IS
EXPECTED TO HAVE FOLLOWING PROPERTIES: A LOW BIOCHEMICAL OXYGEN
DEMAND AND LITTLE POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS
SYSTEMS, A HIGH POTENTIAL TO AFFECT SOME AQUATIC ORGANISMS, A HIGH
POTENTIAL TO AFFECT SECONDARY WASTE TREATMENT MICROBIAL METABOLISM,
A MODERATE POTENTIAL TO AFFECT GERMINATION AND/OR EARLY GROWTH OF
SOME PLANT S, A LOW POTENTIAL TO PERSIST IN THE ENVIRONMENT, A LOW
POTENTIAL TO BIOCONCENTRATE. AFTER DILUTION WITH A LARGE AMOUNT OF
WATER, FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT
EXPECTED T O CAUSE ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: NONE.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.